Rapid Polycyclic Polymerization of Linear Dicyanoacetylene Activated by Pressure
作者单位:Center for High Pressure Science and Technology Advanced Research Geophysical Laboratory Carnegie Institution of Washington
会议名称:《中国化学会第七届全国结构化学学术会议》
会议日期:2016年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
摘 要:Pressure-induced polymerization has been documented for a wide variety of crystalline molecular solids,yet precise mechanistic details of the reactions are not fully understood and the direct characterization of recovered products is *** we study the high-pressure behavior of linear dicyanoacetylene(CN)up to 10 GPa in diamond anvil