Synthesis of Ferrocenophanes with tetrazine side chain and its investigation on anion recognization
作者单位：Department of ChemistryCapital Normal University
会议名称：《中国化学会第十三届全国有机合成化学学术研讨会》
会议日期：2016年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：北京市教育委员会科技计划项目资助(025135303700/035) 科技部国家支撑计划-科研用核心试剂产业化示范(2009BAK61B04)
关 键 词：Tetrazine Ferrrocenophane anion recognition Uv-vis spectrum
摘 要：In this paper,1,1’-ferrocenedicarbonyl chloride was prepared via three steps of acetylation,oxidation and halogenation;At the same time,N,N-bis(3-aminoalkyl)-1,2,4,5-tetrazine-3,6-diamine(a1,a2,a3) were prepared by the reaction of 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine with ethyldiamine,propane-1,3-diamine and butane-1,4-diamine;1,1’-Ferrocenedicarbonyl chloride reacted with a1,a2,a3 respectively to form tetrazine ferrocenophanes(f1,f2,f3) which were confirmed by H-NMR、C-NMR、IR and *** properties on anions of f1,f2,f3 were investigated by Uv-vis *** results showed that maximum absorption peak of four anions(CO,OH-,PO,BO) possessed obvious difference on visible zone.