甲基三氧化铼催化烯烃环化的机理研究(英文)
作者单位:大连理工大学化工与环境生命学部 Department of ChemistryTohoku University
会议名称:《第十七届全国金属有机化学学术讨论会》
会议日期:2012年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:正The methyltrioxorhenium(MTO)-catalyzed epoxidation of olefin(oxygen transfer)with H2O2 has been a fascinating research topic for a long time because of its not only scientific interest but also industrial *** is arguable whether such oxygen-transfer reaction follows concerted or stepwise *** related mechanistic studies usually imply the rhenium peroxides,such as I in Chart 1,as an active species in the