A 3-D Supramolecular Network with 1-D Cation Metal-organic Coordination Polymers,and Diverse Motifs from Hydrogen-bonded[M(H2O)4]-Carboxylates
会议名称:《重庆市化学化工学会2009学术年会》
会议日期:2009年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
摘 要:The self-assembly of metal-organic supramolecular network from transition metal ions and organic moieties is in rapid progress because of their interesting molecular structures as well as their potential applications(such as catalysis, molecular recognition and their optical property) in the area of functional materials.M(HO) hydrated ion is an interesting subject for the investigation of the coordination behavior of metal ions and mixed ligands in water solution, and the construction of metal-organic hybrid materials in crystal engineering4].Although ditopic symmetry 1,