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Palladium-Catalyzed Asymmetric Hydrophosphorylation of Norbo...

Palladium-Catalyzed Asymmetric Hydrophosphorylation of Norbornenes

作     者:Qing Xu ab and Li-Biao Han ,a a National Institute of Advanced Industrial Science and Technology(AIST),Tsukuba,Ibaraki 305-8565,Japan, b College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035 

会议名称:《中国化学会第28届学术年会》

会议日期:2012年

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

关 键 词:H-Phosphonates Asymmetric Hydrophosphorylation Norbornenes Chiral Organophosphorus Compounds Pd Catalysis 

摘      要:正Chiral organophosphorus compounds are highly useful in biochemistry,organic synthesis,and asymmetric ***,successful enantioselective preparation of these compounds via metal-catalyzed asymmetric addition of H-P bonds to alkenes is *** other H-phosphonates,which can not undergo metal-catalyzed addition to a

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