Synthesis, structural characterization and terahertz spectroscopic of group 11 complexes with 1,10-phenanthroline and 1,3-bis(diphenylphosphino)propane
作者单位：Department of Chemistry Capital Normal University
会议名称：《2015年第十四届全国应用化学年会》
会议日期：2015年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
关 键 词：group 11 complexes 1,10-phenanthroline(phen) 1,3-bis(diphenylphosphino)propane(dppp) luminescent THZ
摘 要：We have synthesized and structurally characterized a series of some new copper(I) halogen and pseudohalogen complexes, [Cu(dppp)(phen)][X](X = BF(1), CFSO(2), NO(3), SCN(4), I(5)). Additionally, {[Ag(dppp)(phen)]·(BF)}(6) has been designed and synthesized by the similar reaction. They have been fully characterized by 1H NMR, elemental analysis, IR, luminescence spectroscopy and terahertz time-domain spectroscopy and determined their structures by X-ray crystallography. Noteworthily, complex 1 has been reported before, but 1 is charactered by UVspectroscopy, luminescence and terahertz time-domain spectroscopy for the first time in this article. Complex 2 is also mononuclear and displays a favorable π-π stacking and can be simplified as twodimensional topology.