Rhodium-and Iridium-Catalyzed Diastereoselective Pudovik Reaction of Optically Pure H-Phosphinate with Aldehydes

作     者：Qing Xu, ab Qiang Li a and Li-Biao Han,b a College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035, b National Institute of Advanced Industrial Science and Technology(AIST),Tsukuba,Ibaraki 305-8565,Japan 

会议名称：《中国化学会第28届学术年会》

会议日期：2012年

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：国家自然科学基金(20902070)资助项目 

关 键 词：Pudovik Reaction Optically Pure H-Phosphinate Diastereoselective Addition Aldehydes Rh or Ir Catalysis 

摘      要：正Pudovik reaction, 1 the addition of P-H compounds to aldehydes and imines,is one of the most general, straightforward,and widely-applied method for the construction of P-C *** to the biological activities and pharmaceutical applications of theα-aminoacid like products and related derivatives,numerous reports and reviews have focused on the react