Strong extraction ability of Task-Specific Ionic Liquids over Conventional Ionic Liquids : An Experimental and Theoretical Study
作者单位：State Key Laboratory of Chemical Engineering and Department of ChemistryEast China University of Science and Technology
会议名称：《中国化学会第十二届全国量子化学会议》
会议日期：2014年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
摘 要：A hydrophobic task-specific ionic liquid designed to extract Cu2+from water was prepared by appending thiourea-substituted alkyl groups to imidazoles and combining the resulting cationic species with *** new ionic liquid was characterized and investigated for metal ion extraction capabilities,compared with conventional ionic *** used in liquid/liquid extraction of Cu2+from aqueous solutions,the metal ion extraction rate increased tremendously in *** surface analysis and Fukui Function indicates that the thiourea group possesses a powerful electronic interaction to metal ion and a strong electron donating ability,which may responsible for the improving in extraction.