Oxidative Coupling:Chemistry between Two "Nucleophiles"

作     者：Aiwen Lei College of Chemistry and Molecular Sciences,Wuhan University,Hubei,P.R.China,430072 

会议名称：《中国化学会第十届全国有机合成化学学术研讨会》

会议日期：2012年

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

摘      要：Our research focuses on developing novel and efficient bond-formation methods catalyzed by transition ***,we are interested in the oxidative coupling,which avoids difficult oxidative addition step and makes bonds between two *** an important character of our research,in-depth understanding toward the reactions is the other ***,we revealed a second transmetallation reaction,which could occur in the Pd-catalyzed coupling reaction as a fundamental *** addition, kinetic studies in our laboratory quantitatively disclosed the rate ofreductive elimination of Csp-Ni-Csp.