Synthesis,Efficiency,and Recyclable Scandium-Complexed Dendritic Nanoreactors on Silica as Lewis Acid Catalyst in Friedel-Crafts Acylation Reactions
作者单位：Department of ChemistryShanghai University
会议名称：《中国化学会全国第十一届有机合成化学学术研讨会》
会议日期：2014年
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
关 键 词：Scandium Complex Dendrimer Nanoreactors Friedel-Crafts Acylation Nanoenvironment.
摘 要：Scandium-complexed dendritic nanoreactors（SCDNS） on silica,featured with mushroom-like dendrites and deep-falling cavities,were evaluated as catalysts for Friedel-Crafts acylation *** results showed the nanoenvironment of SCDNS played a dominant role in improving the activity of *** fluorobenzene could be acylated smoothly,which hardly occurs in most ***,the catalysts can be easily recovered by simple filtration and reused for several times without significant loss of activity.