Separation of Inorganic Anions on A Chemically-Bonded 18-Crown-6 Ether Stationary Phase in Capillary Ion Chromatography
作者单位:Department of ChemistryFaculty of EngineeringGifu University1-1 YanagidoGifu 501-1193Japan
会议名称:《第六届上海国际分析化学研讨会》
会议日期:2012年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 0703[理学-化学]
关 键 词:Ion chromatography 18-crown-6 ether inorganic anions retention behavior
摘 要:正Introduction and Results Crown ethers,typically 18-crown-6 ether (18C6E),have been used to improve the resolution of cations in ion chromatography [1-4]. For example,the addition of 18C6E in the eluent apparently increases the retention of potassium ion to improve the resolution. This is because the association constant of complexation between