Re-investigation of the Double Lithiation of Stannocene
作者单位：Department of ChemistryMoscow State UniversityLeninskie Gory 1bldng. 3Moscow 119992Russian Federation Department of ChemistryNorthwest University Xi’an 710069 Department of Chemistry Moscow State University Leninskie Gory 1bldng.3Moscow 119992Russian Federation
会议名称：《中国化学会第四届有机化学学术会议》
会议日期：2005年
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要：正Among the properties of stannocene [biscyclopentadienyltin（Ⅲ）] its ability to undergo double lithiation was reported. This rather intriguing advantage, however, has never been applied in practice, except to perform the silylation and even stepwise double silylation reactions. Nevertheless, since 1983 （LiC5H4）2Sn has been mentioned in related reviews and dictionaries of organometallic compounds.