Solubility prediction of HCl-MgCl2-H2O system at 50℃ using the ion-interaction model
会议名称:《中国化学会第十三届全国化学热力学和热分析学术会议》
会议日期:2006年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
关 键 词:Pitzer’s ion-interaction model Activity Coefficient Manufacture process Solubility prediction
摘 要:正The component solubility of HCl-MgCl2-H2O system at 50℃ was calculated by using Pitzer’s ion-interaction model and its extended HW model. The values of the parameters of β(0), β(1),C(?) of HCl and MgCl2 were obtained from optimization of the literature data, and θMgH and ψMgHCl were derived by coupling activity coefficient with solubility data. The comparison between the results by using the