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Syntheses,Crystal Structure,and Characterizations of Polysul...

Syntheses,Crystal Structure,and Characterizations of Polysulfide Compound:Ba4Sb4S11

作     者:Zhong-Zhen Luo,Chen-Sheng Lin,Hao Zhang,Wei-Long Zhang, Wen-Dan Cheng~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Mater,the Chinese Academy of Sciences,Fuzhou,Fujian 350002. Graduate School of the Chinese Academy of Sciences,Beijing,100039. 

会议名称:《中国化学会第六届全国结构化学学术会议》

会议日期:2012年

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

摘      要:Ternary Ba-Sb-S systems have been well studied and many compounds,including BaSbS,BaSbS, etc.,have been synthesized over the past 30 *** these compounds,as there are no S-S bonds in the structures,the oxidation state of all S atoms is 2-.The ternary polysulfide compound,BaSbS,was synthesized by using a conventional high-temperature solid-state reaction method in evacuated quartz tubes.

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