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Preparation,characterization and thermal properties of terne...

Preparation,characterization and thermal properties of ternery lanthanide complexes with halogen-benzoic acid and 1,10-phenanthroline

作     者:Juan-Fen Wang~(1 2) Ning Ren~3 Jian-Jun Zhang~(1 2*) Ke-Zhong Wu~2 (1 Experimental Center Hebei Normal University Shijiazhuang 050016 P.R.China.) (2 College of Chemistry & Material Science Hebei Normal University Shijiazhuang 050016 P.R. China) (3 Department of Chemistry Handan College Handan 056005 P.R.China) 

会议名称:《中国化学会第十五届全国化学热力学和热分析学术会议》

会议日期:2010年

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:supported by the National Natural Science Foundation of China(No.20773034) the Natural Science Foundation of Hebei Province(No.B2007000237) 

关 键 词:lanthanide complexes halogen-benzoic acid 1,10-phenanthroline fluorescence heat capacity 

摘      要:正The two new series of solid ternery lanthanide complexes of Ln(Ⅲ)(Ln = Eu,Tb,Ho) were synthesized with 2,3-dichlorobenzoate(2,3-DCIBA) or 2-chloro-4-fluorobenzoate(2-Cl-4-FBA) as the anion ligand,and 1,10-phenanthroline(phen) as the neutral *** complexes

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