In situ Crystallization of Ionic Liquids [EMIM][NO3] from Its Supercooled Liquid under Extreme Conditions
作者单位:The High Pressure Research Center of Science and Technology Zhengzhou University of Light Industry Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences
会议名称:《第十八届中国高压科学学术会议》
会议日期:2016年
学科分类:080701[工学-工程热物理] 08[工学] 0807[工学-动力工程及工程热物理]
摘 要:[EMIM][NO]is a halogen-free ionic liquid and relatively hydrolysis-stable *** could be an interesting alternative for industrial application due to the fact that it avoids the liberation of toxic and corrosive HF into the *** this work,we are concerned with the phase transitions of[EMIM][NO]by using Raman scattering as a function of pressure or *** significant changes in spectra show that[EMIM][NO3]undergoes a liquid to solid phase transition at 0.9