Exploring New Reactions involving Isocyanide
作者单位：State Key Laboratory of Respiratory DiseaseGuangzhou Institutes of Biomedicine and HealthChinese Academy of Sciences
会议名称：《中国化学会全国第十一届有机合成化学学术研讨会》
会议日期：2014年
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：国家自然科学基金(No.20942001 21072190 21272233)资助项目
关 键 词：Isocyanide Palladium Imidoyl radical Heterocycle
摘 要：Isocyanides have been recognized as versatile building blocks in Lewis or Bronsted acid-promoted reactions,including Passerini and Ugi mutlicomponent reactions,complex amide synthesis and ***,their application in transition-metal-catalyzed imination,carboxyamidation,amidination reactions,and cyanation,acting as isoelectronic equivalents of CO,is relatively *** this conference,we will report our recent research on some new reactions involving imidoyl palladium and imidoyl radical intermediates for the synthesis of N-heterocycles.