Copper-Catalyzed Dehydrogenative Cross-Coupling of Benzothiazoles with Thiazoles and Polyfluoroarene
作者单位:Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences345 Lingling Road Shanghai 200032 China
会议名称:《中国化学会第十二届全国氟化学会议》
会议日期:2012年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:financially supported by the NSFC(Nos 21172242,20902100,20832008) the National Basic Research Program of China(973 Program)(No.2012CB821600) SIOC
摘 要:正As an attractive alternative to traditional cross-coupling in construction of carbon-carbon(C-C) bonds, transition-metal-catalyzed direct functionalization of C-H bonds has gained considerable *** particular,dehydrogenative cross-coupling from two simple C-H bonds represents a most efficient and straightforward access to the target molecules,since this tandem oxidation of C-H bonds avoids the