The dissolution properties of 6b-Nitrohexahydro-2H-1,3,5-trioxacyclopenta[cd]-pentalene-2,4,6-triyl trinitrate（NHTPN） in N,N-dimethyl formamide（DMF）
作者单位：Key Laboratory of Space Applied Physics and Chemistry of Ministry of Education Department of Applied Chemistry School of Science Northwestern Polytechnical University
会议名称：《第十七届全国化学热力学和热分析学术会议》
会议日期：2014年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
关 键 词：6b-Nitrohexahydro-2H-1,3,5-trioxacyclopenta[cd]-pentalene-2,4,6-triyl trinitrate(NHTPN) Calvet microcalorimeter Dissolution Kinetics
摘 要：The enthalpy of dissolution of 6b-Nitrohexahydro-2H-1, 3, 5-trioxacyclopenta[cd]-pentalene-2, 4, 6-triyl trinitrate（NHTPN）（CAS: 1428236-72-9） in N,N-dimethyl formamide（DMF） was measured by means of a DC08 Calvet microcalorimeter at 298.15 K. Empirical formulae for the calculation of the enthalpy of dissolution, relative partial molar enthalpy, and relative apparent molar enthalpy were obtained from the experimental data of the enthalpies of dissolution of NHTPN in DMF. The kinetic equation that describes the dissolution process of NHTPN in DMF at 298.15 K is determined as.