Four Polynuclear MnⅡ Coordination Polymers Based on 5-tert-butyl Isophthalic Acid and Flexible N-donor Co-ligands:Synthesis,Structures and Magnetic Properties

作     者：Min-Le Han,Lu-Fang Ma *,Jian-Hua Qin,Li-Ya Wang* College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang,471022 

会议名称：《中国化学会第28届学术年会》

会议日期：2012年

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (21073082 and 21071074) Program for New Century Excellent Talents in University 

关 键 词：5-Tert-butyl isophthalic acid Mn II coordination polymers Magnetic properties 

摘      要：Four new Mn II coordination polymers,[Mn 1.5（tbip）（Htbip）（bib）].2H2O（1）,[Mn 4（tbip） 4（bip）].2H2O（2）,[Mn2（tbip）2（bbp）（H2O）]（3）,and [Mn3（tbip）3（bix）2]（4）（H2tbip = 5-tert-butyl isophthalic acid;bib = 1,4-bis（imidazol）butane,bip = 1,3-bis（imidazol）propane,bbp = 1,3-bis（benziminazol）propane,bix = 1,4-bis（imidazol-1-ylmethyl）benzene） have been synthesized under hydrothermal conditions.1 exhibits a pcu topology containing [Mn3（COO）6] units.2 shows a 4-connected dia topology containing alternate mono/trinuclear Mn II units.3 features a 3D 8-connected net with a（36.4 16.5 6） topology showing [Mn4（COO）6（H2O）2] 2+ units.4 has a 3D 8-connected net hex topology containing [Mn3（COO） 4 ] 2+ ***,the magnetic properties of four complexes were investigated.