Oxidative Cleavage of Double Bond Catalyzed by Gold（Ⅰ）Complexes in Air and Water
会议名称：《中国化学会第四届有机化学学术会议》
会议日期：2005年
学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
摘 要：正Gold particle as catalyst to transfer oxygen was studied and utilized ***, gold compounds was also used as homogeneous catalyst to form C-C bonds. Herein we discovered that gold（I） salt with some ligands to form complexes could be used to sever C=C bonds to aldehydes or ketones. The conditions of these reactions are very mild and water can be applied as solvent, which is very benign to circumstances.