Palladium-or Copper-Catalyzed Aerobic Oxidative Synthesis of Imines from Alcohols and Amines under Ambient Conditions

作     者：Haiwen Tian,Lan Jiang,Xiaochun Yu and Qing Xu* College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035 

会议名称：《中国化学会第28届学术年会》

会议日期：2012年

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：国家自然科学基金(20902070) 浙江省自然科学基金(Y4100579) 浙江省钱江人才计划(QJD0902004)资助项目 

关 键 词：Imines Alcohols Amines Aerobic Oxidative Reaction Pd or Cu catalysis 

摘      要：正Imines are a class of nitrogen compounds of high significance in chemistry.For the high reactivity of the C=N double bond,they are both important nitrogen sources and key intermediates in various types of transformations. Therefore,synthesis and applications of imines are essentially the ever-appealing topics in chemistry.However, challenges still remain in the academic researches. Despite other progresses for imine synthesis,traditional condensation of aldehydes or ketones with amines is most often the method of choice.1 Since aldehydes and