Helical Double Stranded Polymers

作     者：Hui-Chun Yang, Shu-Yi Lin, Hsiao-Ching Yang, Nai-Ti Lin,Lun Tsai, Chun-Hsian Chen, and Tien-Yau Luh Department of Chemistry and Institute of Polymer Science and Engineering, National Taiwan University, Taipei, Taiwan 106 Institute of Chemistry, Academia Sinica, Nangang, Taipei, Taiwan 115 Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300 

会议名称：《中国化学会第十三届金属有机化学学术讨论会》

会议日期：2004年

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

摘      要：正 The synthesis of helical double stranded polymers 2 from the ring opening metathesis polymerization of bisnorbornene derivatives 1 will be described. Characterization of 2 by spectroscopic methods and stm will be described. Molecular dynamic simulation of 2 will be presented. Base-promoted hydrolysis of 2 yielded the corresponding single stranded polymer 3 and ferrocene dicarboxylic acid. The use of a single stranded polymer as a template for the synthesis of double stranded polymer will be discussed.