Novel Supramolecular Assemblies Based on[CdCl4]2-Induced Coordination of Lanthanide Metal Ions to Cucurbit[5]uril
作者单位：Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou ProvinceGuizhou University
会议名称：《全国第十六届大环化学暨第八届超分子化学学术讨论会》
会议日期：2012年
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：国家自然科学基金项目(No.20961002 No 21101037)
关 键 词：cucurbituril lanthanide cation inorganic inducers coordination polymers
摘 要：In one of our previous works,we used to report a crystal structure of a compound of hydronium dichloroferrate chloride adducts with cucurbituril,we found that it is a novel supramolecular architecture of trans-[FeCl(HO)] with Q[6].In the Ln-Q[6]and Ln-Q[7]systems,the[MCl](M=Cd,Zn) can present thehoneycomb effectand form the honeycomb hallows in which the one-dimensional supramolecular chains or tubes constructed of Lncations and Q[6]or Q[7]molecules through direct