Synthesis and Cystal Sructure of the Custer [Fe2(CO)4(μ,η~2-COC6H5)(μ4,η~3-CH3C(CH2PPh(CH2PPh2)2))]
会议名称:《中国化学会第九届全国络合催化学术讨论会》
会议日期:2005年
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:正Transition metal carbonyl cluster compounds have attracted significant interest for a variety of reasons including, inter alia, the transition from molecular to bulk metallic properties which should ensue upon increasing cluster size, as models for metal surfaces in chemisorption and catalysis, and as precursors for metal narticles active in heterogeneous catalysis . The tripodal