A Multiple-Twin-Crystal Nature of the Branching Cu2O Particles by Electrodeposition

作     者：Zhi-Yuan Jiang Yan-Yun Ma Qin Kuang Shu-Hong Zhang Zhao-Xiong Xie Rong-Bing Huang Lan-Sun Zheng State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China. 

会议名称：《中国化学会第五届全国结构化学学术会议》

会议日期：2007年

学科分类：081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

摘      要：Recently years,considerable attentions have been focused on the various polyhedron-based branching particles due to their fundamental significance and their widespread potential ***,the knowledge of the original nature and the growth mechanisms for these complicated structures are still *** this paper,polyhedron-based branching CuO micro-crystals have been prepared via electrodeposition process without any surfactant at the room *** electron diffraction pattern of the branching CuO micro-crystals can be indexed as a single crystal as many other polydedron-based branching crystals *** carefully analyzing the intensities of the diffraction spots,we conclude that the crystal twinning (stacking fault)is responsible for the well-shaped CuO micro-crystals,which indicate that these branching particles in fact multiple twinned crystals,other than perfect single *** could be anticipated that the crystal twinning(or the stacking fault)could be the common phenomena in the single-crystal-like branching particles.