Dinuclear terephthalato-bridged nickel(Ⅱ) complex:structural characterization and magnetic property
会议名称：《13th Asian Chemical Congress》
会议日期：2009年
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：supported by Beijing Natural Science Foundation(grant no.2092010) Beijing Municipal Education Commission research program(KM200810028009)
关 键 词：nickel dinuclear complexes benzimidazole magnetic property
摘 要：Complexes containing imidazole and benzimidazole have been studied by several groups. Among them,the tripod-like ligand tris(2-benzimidazolylmethyl)amine(ntb)has been studied to model the active site of superoxide ***,we report the synthesis,structure and magnetic property of a terephthalato-bridged dinuclear nickel(Ⅱ)complex [Ni(ntb)(μ-tp)(HO)](NO)·8CHOH·2HO.