The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes:A Computational Study
作者单位:School of Chemistry and Chemical EngineeringChongqing University Dalian Institute of Chemical Physics Chinese Academy of Sciences
会议名称:《中国化学会第九届全国有机化学学术会议》
会议日期:2015年
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:正The mechanism and regioselectivity of the[RhⅢCl2Cp*]2-catalyzed C-H bond functionalization and N-O bond cleavage of quinoline N-oxide with alkynes were studied by using