Recent advances in synthesis of organosilicons via radical strategies

作     者：Xueping Zhang Jingkun Fang Chun Cai Guoping Lu Xueping Zhang;Jingkun Fang;Chun Cai;Guoping Lu

作者机构：School of Chemical EngineeringNanjing University of ScienceTechnologyNanjing 210094China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2021年第32卷第4期

页      面：1280-1292页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the Fundamental Research Funds for the Central Universities(No.30920021120) Key Laboratory of Biomass Energy and Material,Jiangsu Province(No.JSBEM201912) the National Natural Science Foundation of China(No.21905089) the Chinese Postdoctoral Science Foundation(No.2019M662775)for financial support 

主　　题：Organosilicon Radical silylation Single electron transfer Hydrogen atom transfer Photoredox Alkyl radical 

摘      要：Organosilicon compounds play an important role in the fields of materials science,pharmacy,and organic *** development of effective approaches for the preparation of these compounds have also become a research focus in organic *** recent years,free radical synthesis of organosilicons has been vigorously developed,which generally has the advantages of milder synthesis conditions,higher yields and selectivity,and free of precious metal catalysts compared with traditional *** article reviews research progresses in the synthesis of organosilico n compounds by free radical pathways since *** most cases,the radical silylation is achieved based on the reaction of silyl radicals,which are triggered by four routes including peroxide,transition-metal-induced peroxide decomposition,alkali,*** alkyl radicals can also initiate the radical silylation for the generation of C(sp^(3))—Si bonds.