Distribution and geochemical significance of dibenzofurans,phenyldibenzofurans and benzo[b]naphthofurans in source rock extracts from Niger Delta basin,Nigeria

作     者：Abiodun B.Ogbesejana Oluwasesan M.Bello Abiodun B.Ogbesejana;Oluwasesan M.Bello

作者机构：Department of Applied ChemistryFederal University Dutsin-MaP.M.B.5001Dutsin-MaKatsina StateNigeria 

出 版 物：《Acta Geochimica》 (地球化学学报（英文）)

年 卷 期：2020年第39卷第6期

页      面：973-987页

核心收录：

学科分类：081803[工学-地质工程] 0709[理学-地质学] 0819[工学-矿业工程] 08[工学] 0818[工学-地质资源与地质工程] 0708[理学-地球物理学] 

基　　金：The authors gratefully acknowledge the State Key Laboratory of Petroleum Resources and Prospecting College of Geoscience China University of Petroleum Beijing China for granting A.B.Ogbesejana an international visiting research fellowship towards this research work. 

主　　题：Dibenzofurans Benzo[b]napthofurans Source rocks Niger delta Gas chromatography-mass spectrometry 

摘      要：The distribution and geochemical significance of dibenzofurans,phenyldibenzofurans and benzo[b]naptho-furans in source rocks from Niger Delta basin,Nigeria,were investigated by Rock-Eval pyrolysis and gas chro-matography--mass spectrometry(GC--MS).The data obtained from the source rocks evaluation showed that the rock samples contained type 1/III kerogen capable of generating oil and gas and were within immature to early mature stage.The relative abundance of the Cor,C1-and C2-dibenzofurans range from 1.75%to 29.82%,27.60%to 40.52%and 29.66%to 6889%,respectively.The diben-zofurans were dominated by C-dibenzofurans.Among the C1-dibenzofurans,2-+3-methyldibenzofuran was the most abundant in the rock samples while 1-methy ldibenzofuran appeared to be the least.The relative abundance of benzo[b]naphtho[1,2-d]furan(1,2]BNF),benzo[b]naph-tha[2,1-d]furan(2.1]BNF)and benzo[b]naphtha[2,3-d]fu-ran([2.3]BNF)in the rock extracts range from 12.01%to 52.58%,32.61%to 75.219%and 10.27%to 52.43%.The wide range of values recorded for the three isomers of benzo[b lnapthofurans in the samples suggest source rocks formed from mixed organic matter.Among the pheny ldibenzofuran isomers,4-pheny ldibenzofuran was the most abundant while 1-phenyldibenzofuran was the least.Phenyldibenzofuran ratio-1(PhFR-1)and pheny ldibenzofuran ratio-2(PhFR-2)values range from 0.13 to 1.20 and 0.11 to 2.11,respectively.The resuls showed that the relative abundance of PhFR-1 and PhFR-2 increase gradually with increasing burial depth and maturity(VRo≤0.77%,MPI-1≤0.62.Tmax s 443℃),and have a good correlations with calculated vitrinite reflectance.MPI-I and maximum Temperature(Tmax)-This range of values suggested immature to early mature source rocks.The source rocks were found to have shale and coul lithologics and deposited in a lacustrine/fuvial deltaic settings within immature to early mature stages based on the distribution of dibenzofurans,pheny ldiben-zofurans and benzo[b]naphthofurans in the source rocks.This study showed that dibenzof urans,phenyldibenzofu-rans and benzo[b]naphthofurans were ffcive in deter-mining the origin,depositional environment and thermal maturity of source rocks in Niger Delta basin,Nigeria.