A Sulfonate-based Metal-organic Framework for the Transformation of CO and Epoxides into Cyclic Carbonates

作     者：XUE Huan LI Tao YIN Qi HUANG Ge LIU Tian-Fu XUE Huan;LI Tao;YIN Qi;HUANG Ge;LIU Tian-Fu

作者机构：College of Chemistry and Materials ScienceFujian Normal UniversityFuzhou 350007China State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2020年第39卷第11期

页      面：2027-2032页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China (No. 21871267) 

主　　题：metal-organic frameworks sulfonate group Lewis metal sites cycloaddition 

摘      要：An interesting metal-organic framework(MOF) PFC-31 was synthesized by a simple solvothermal reaction. X-ray crystallography reveals that PFC-31 crystallizes in monoclinic system, space group P21/c with a = 6.8410(17), b = 20.123(5), c = 7.689(2) ?, β = 104.239(7)°, V = 1026.0(5) ?3, Z = 2, C16 H22 CuN4 O8 S2, Mr = 526.03, μ = 1.322 mm-1, Dc = 1.703 g/cm3, F(000) = 542, GOOF = 1.214, R = 0.0975 and w R = 0.2324. According to X-ray analysis, PFC-31 shows one-dimensional chain constructed by Cu(Ⅱ) centers coordinating with two pyridine groups, two sulfonate groups and two DMF molecules. Owing to the orderly functionalized sulfonate group and Lewis metal sites, PFC-31 exhibits good catalytic capability for CO2 cycloaddition of epoxide under normal pressure and temperature.