Engineering heterogenous catalysts for chemical CO_(2) utilization:Lessons from thermal catalysis and advantages of yolk@shell structured nanoreactors

作     者：Cameron Alexander Hurd Price Tomas Ramirez Reina Jian Liu Cameron Alexander Hurd Price;Tomas Ramirez Reina;Jian Liu

作者机构：DICP-Surrey Joint Centre for Future MaterialsDepartment of Chemical and Process EngineeringUniversity of SurreyGuildfordSurrey GU27XHUK State Key Laboratory of CatalysisDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2021年第30卷第6期

页      面：304-324,I0008页

核心收录：

学科分类：0820[工学-石油与天然气工程] 083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0808[工学-电气工程] 081705[工学-工业催化] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 

基　　金：Financial support was provided by the Chinese Academy of Sciences–The World Academy of Sciences(CAS-TWAS)president fellowship 

主　　题：Yolk@shell CO_(2)utilization Reforming Hydrogenation Confinement effect 

摘      要：The development of catalytic materials for the recycling CO_(2) through a myriad of available processes is an attractive field,especially given the current climate *** there is increasing publication in this field,the reported catalysts rarely deviate from the traditionally supported metal nanoparticle morphology,with the most simplistic method of enhancement being the addition of more metals to an already complex *** catalysts,especially yolk@shell catalysts with hollow voids,offer answers to the most prominent issues faced by this field,coking and sintering,and further potential for more advanced phenomena,for example,the confinement effect,to promote selectivity or offer greater protection against coking and *** work serves to demonstrate the current position of catalyst development in the fields of thermal CO_(2) reforming and hydrogenation,summarizing the most recent work available and most common metals used for these reactions,and how yolk@shell catalysts can offer superior performance and survivability in thermal CO_(2) reforming and hydrogenation to the more traditional ***,this work will briefly demonstrate the bespoke nature and highly variable yolk@shell ***,this review aims to illuminate the spatial confinement effect and how it enhances yolk@shell structured nanoreactors is presented.