Solid phase microwave-assisted fabrication of Fe-doped ZIF-8 for single-atom Fe-N-C electrocatalysts on oxygen reduction

作     者：Xinlong Xu Xiaoming Zhang Zhangxun Xia Ruili Sun Huanqiao Li Junhu Wang Shansheng Yu Suli Wang Gongquan Sun Xinlong Xu;Xiaoming Zhang;Zhangxun Xia;Ruili Sun;Huanqiao Li;Junhu Wang;Shansheng Yu;Suli Wang;Gongquan Sun

作者机构：Division of Fuel Cells and BatteryDalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Key Laboratory of Fuel Cells&Hybrid Power SourcesChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of SciencesBeijing 100049China Mössbauer Effect Data CenterDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Department of Materials ScienceJilin UniversityChangchun 130012JilinChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2021年第30卷第3期

页      面：579-586页

核心收录：

学科分类：0820[工学-石油与天然气工程] 0808[工学-电气工程] 081705[工学-工业催化] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 

基　　金：financially supported by the Key Program of the Chinese Academy of Sciences(KFZD-SW-419),China the Major Research Plan of the National Natural Science Foundation of China(91834301),China 

主　　题：Microwave-assistant Zeolitic imidazolate framework-8 Fe single atoms Electrocatalysts Oxygen reduction reaction 

摘      要：Fe-N-C endowed with inexpensiveness,high activity,and excellent anti-poisoning power have emerged as promising candidate catalysts for oxygen reduction reaction(ORR).Single-atom Fe-N-C electrocatalysts derived from Fe-doped ZIF-8 represent the top-level ORR ***,the current fabrication of Fe-doped ZIF-8 relies on heavy consumption of time,energy,cost and organic ***,we develop a rapid and solvent-free method to produce Fe-doped ZIF-8 under microwave irradiation,which can be easily amplified in combination with *** rational pyrolysis,Fe-N-C catalysts with atomic FeN4 sites well dispersed on the hierarchically porous carbon matrix are obtained,which exhibit exceptional ORR performance with a half-wave potential of 0.782 V(*** hydrogen electrode(RHE))and brilliant methanol *** assembled direct methanol fuel cells(DMFCs)endow a peak power density of 61 mW cm^(-2) and extraordinary stability,highlighting the application perspective of this strategy.