Two new pseudo-isomeric nickel(Ⅱ)metal-organic frameworks with efficient electrocatalytic activity toward methanol oxidation

作     者：Shan Liu Xiao Wang Hong-Guang Yu Ya-Pan Wu Bo Li Ya-Qian Lan Tao Wu Jian Zhang Dong-Sheng Li Shan Liu;Xiao Wang;Hong-Guang Yu;Ya-Pan Wu;Bo Li;Ya-Qian Lan;Tao Wu;Jian Zhang;Dong-Sheng Li

作者机构：College of Materials and Chemical EngineeringKey Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang443002China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2021年第40卷第2期

页      面：489-498页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the National Natural Science Foundation of China(Nos.21971143,21673127,21671119,51572152 and 21805165) the Program of the Ministry of Education of China for Introducing Talents of Discipline to Universities(No.DT20015) Innovation Team of Young and Middle-aged Research(ITOYMR)in the Higher Education Institutions of Hubei Province(No.T201904) 

主　　题：Nickel(Ⅱ) MOFs Composite materials Electrocatalysis Methanol oxidation 

摘      要：Searching for non-noble metal catalysts with high activities and low price is critical to the commercialization of methanol oxidation in the process of fuel ***,two new pseudo-isomeric Ni metal-organic frameworks(Ni-MOFs)(CTGU-17/CTGU-18)have been prepared with 1,4-naphthalenedi-carboxylate(H_(2)NDC),4,4’-dipyridyl amine(DPA)and Ni(ClO_(4))_(2)under hydrothermal *** phase contains one water molecule,but differs dramatically in its bonding to the framework,resulting in different topological networks with fourfold interpenetrating 4-connected dia net(CTGU-17)and(3,7)-connected net(CTGU-18)and diverse electrocatalytic performance for methanol oxidation reaction(MOR).Remarkably,by combining each MOF with the conductive additive,acetylene black(AB),a composite material,AB&CTGU-18(2:4)was confirmed to have an excellent performance for MOR with a high mass specific peak current of 442.3 mA·mg^(-1).The enhanced electrocatalytic activities and robustness might be attributed to the synergetic effect of acetylene black and the active metal centers of MOFs particles for methanol *** present work would provide a new insight for the rational design of MOFs-based composites with enhanced methanol oxidation reaction performance.