Design and Application of Indole-Based Allylic Donors for Pd-Catalyzed Decarboxylative Allylation Reactions

作     者：Qing-Qing Hang Si-Jia Liu Lei Yu Ting-Ting Sun Yu-Chen Zhang Guang-Jian Mei Feng Shi Qing-Qing Hang;Si-Jia Liu;Lei Yu;Ting-Ting Sun;Yu-Chen Zhang;Guang-Jian Mei;Feng Shi

作者机构：School of Chemistry and Materials ScienceJiangsu Normal UniversityXuzhouJiangsu 221116China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2020年第38卷第12期

页      面：1612-1618页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We are grateful for financial support from NSFC(Nos.21772069,21831007 and 21702077) the Natural Science Founda-tion of Jiangsu Province(No.BK20170227) Six Kinds of Talents Project of Jiangsu Province(No.SWYY-025) 

主　　题：palladium catalyzed allyl 

摘      要：of main observation and conclusion A new class of indole-based allylic donors have been designed and developed for palladium-catalyzed decarboxylative *** addition,the first application of these indole-based allylic donors in palladium-catalyzed decarboxylative[3+2]cydoaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines,*** approach represents the first design of indole-based allylic donors,which is helpful for settling the challenge of designing and developing new class of heterocycle-based allylic donors for Pd-catalyzed decarboxylative allylation ***,the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.