Aluminum and phosphorus codoped “superaerophobic” Co3O4 microspheres for highly efficient electrochemical water splitting and Zn-air batteries

作     者：Xian-Wei Lv Yuping Liu Wenwen Tian Lijiao Gao Zhong-Yong Yuan Xian-Wei Lv;Yuping Liu;Wenwen Tian;Lijiao Gao;Zhong-Yong Yuan

作者机构：National Institute for Advanced MaterialsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)College of ChemistryNankai UniversityTianjin 300071China 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2020年第29卷第11期

页      面：324-331页

核心收录：

学科分类：0820[工学-石油与天然气工程] 0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(21421001,21573115,21875118) the Natural Science Foundation of Tianjin(17JCYBJC17100,19JCZDJC37700)。 

主　　题：Trifunctional electrocatalysts Co3O4 Overall water splitting Zn-air batteries "Superaerophobic"surface Anion-cation double doping 

摘      要：Multifunctional non-precious catalysts for hydrogen/oxygen evolution reaction(HER/OER) and oxygen reduction reaction(ORR) constitute the bottleneck in the applications in electrochemical overall water splitting(OWS) and Zn-air batteries. Herein, a trifunctional electrocatalyst of urchin-like Al,P-codoped Co3O4 microspheres supported on Ni foam(denoted as AP-CONPs/NF) was fabricated via a hydrothermal process and subsequent low-temperature annealing and phosphorization, exhibiting enhanced OER, HER and ORR activities compared with single-doped and undoped samples. Their surface self-organized microstructure and excellent superaerophobic feature make a high bubble repellency, which boost diffusion of reactants and electrolyte-electrode intimate contact. The codoping of Al and P elements into Co3O4 betters right the balance among surface chemical state, the increased oxygen vacancies and the promoted charge transfer. Encouraged by these synergistic advantages, the AP-CONPs/NF was further employed as excellent bifunctional electrodes for the OWS(low cell voltage of 1.57 V at 10 mA cm-2) and as air cathode for rechargeable Zn-air batteries(high power density of 89.1 mW cm-2), which demonstrates a great feasibility for practical applications.