Simple manganese carbonyl catalyzed hydrogenation of quinolines and imines

作     者：Zelong Wang Lei Chen Guoliang Mao Congyang Wang Zelong Wang;Lei Chen;Guoliang Mao;Congyang Wang

作者机构：Beijing National Laboratory for Molecular SciencesCAS Key Laboratory of Molecular Recognition and FunctionCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of SciencesBeijing 100049China Provincial Key Laboratory of Oil&Gas Chemical TechnologyCollege of Chemistry and Chemical EngineeringNortheast Petroleum UniversityDaqing 163318China Physical Science LaboratoryHuairou National Comprehensive Science CenterBeijing 101400China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2020年第31卷第7期

页      面：1890-1894页

核心收录：

学科分类：07[理学] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(No.21772202,21831008) Beijing Municipal Science&Technology Commission(No.Z191100007219009) Beijing National Laboratory for Molecular Sciences(No.BNLMS-CXXM201901)。 

主　　题：Manganese Hydrogenation Quinolines Imines Homogeneous catalysis 

摘      要：Manganese-catalyzed hydrogenation of unsaturated molecules has made tremendous progresses recently benefiting from non-innocent pincer or bidentate ligands for manganese.Herein,we describe the hydrogenation of quinolines and imines catalyzed by simple manganese carbonyls,Mn2(CO)10 or MnBr(CO)5,thus eliminating the prerequisite pincer-type or bidentate ligands.