Syntheses,Crystal Structures and Fluorescent Properties of Two Zinc Complexes Assembled by Bis(imidazol)Ligands

作     者：吕梦影 吕丛 闫国松 周实 姜维 刘博 李秀梅 LV Meng-Ying;LV Cong;YAN Guo-Song;ZHOU Shi;JIANG Wei;LIU Bo;LI Xiu-Mei

作者机构：Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University)Ministry of EducationChangchun 130103China Faculty of ChemistryTonghua Normal UniversityTonghua 134002China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2020年第39卷第10期

页      面：1885-1891,1745页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the Science and Technology Development Plan of Jilin Province(2015052006JH) Graduate Innovation Program of Jilin Normal University(201939) 

主　　题：hydrothermal synthesis crystal structure Zn(Ⅱ)complex 1 4-bis(imidazol-1-yl)-benzene 

摘      要：Two new complexes[Zn(nph)(bix)]n·nH2O(1)and[Zn(nba)2(bix)]n(2)(H2nph=4-nitrophthalic acid,Hnba=4-nitrobenzoic acid,bix=1,4-bis(imidazol-1-yl)-benzene)have been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,fluorescence spectrum,single-crystal and power X-ray *** 1 exhibits a three-dimensional(3D)framework,which is stabilized through C–H…O hydrogen bonds andπ-πstacking *** 2 shows a zero-dimensional structure,which is further extended into a three-dimensional supramolecular structure through C–H…O and C–H…N hydrogen bonding interactions.