Uniform corrosion behavior of FeCrAl alloys in borated and lithiated high temperature water

作     者：Fangqiang Ning Xiang Wang Ying Yang Jibo Tan Ziyu Zhang Dan Jia Xinqiang Wu En-Hou Han Fangqiang Ning;Xiang Wang;Ying Yang;Jibo Tan;Ziyu Zhang;Dan Jia;Xinqiang Wu;En-Hou Han

作者机构：CAS Key Laboratory of Nuclear Materials and Safety AssessmentLiaoning Key Laboratory for Safety and Assessment Technique of Nuclear MaterialsInstitute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China ATF R&D Project DepartmentChina Nuclear Power Technology Research Institute Co.Ltd.Shenzhen 518026China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2021年第70卷第11期

页      面：136-144页

核心收录：

学科分类：080503[工学-材料加工工程] 0817[工学-化学工程与技术] 0806[工学-冶金工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0802[工学-机械工程] 0801[工学-力学（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：jointly supported by the National Natural Science Foundation of China the National Science and Technology Major Project[2017ZX06002003-004-002] the Key Programs of the Chinese Academy of Sciences[Research on the Development of Nuclear Power Materials and Service Security Technology,ZDRW-CN-2017-1] 

主　　题：FeCrAl Alloys High temperature corrosion Oxidation SEM TEM 

摘      要：The uniform corrosion behavior of model FeCrAl alloys as well as commercial Zircaloy-4 as reference material were investigated in 360℃borated and lithiated *** results reveal that FeCrAl alloys exhibited better corrosion resistance than *** is found that the oxide films formed on the FeCrAl alloys are composed of outer Fe_(3)O_(4)layer,inner layer consisting of compact spinel layer and porous spinel layer,and transition layer containing Al-Cr-rich oxides and matrix enriched with Fe°.The spinel oxides in the inner layer are FeFe_(2-x-y-z)Cr_(x)Al_(y)MozO_(4).The corrosion mechanism of FeCrAl alloys in high temperature water is discussed.