Novel hybrids of Cu^(2+) ternary complexes of salicylidene-amino acid Schiff base with phenanthroline(or bipyridine) intercalated in Mg/Al-NO_3-layered double hydroxide

作     者：Ming-Zhao Wang Ying Li Jin-Jin Ji Gai-Ling Huang Xin Zhang Si-Hui Li Xiao-Jing Yang 

作者机构：College of ChemistryBeijing Normal University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2013年第24卷第7期

页      面：593-596页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by Beijing Municipal Natural Science Foundation(No.2112022) Key Laboratory of Radiopharmaceuticals of Ministry of Education(College of Chemistry, Beijing Normal University) and Analytical and Testing Center of Beijing Normal University 

主　　题：Layered double hydroxides Ternary copper complexes Intercalation Characterization Stability in solution 

摘      要：Four Cu2＋ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline （Phen） or 2,2＇- bipyridine （Bipy） were successfully intercalated in interlayer galleries of Mg/AI-NO3-1ayered double hydroxide （LDH） by the swelling-restored method. The hybrids were characterized by elemental analysis, X-ray diffraction, FT-IR spectra, UV-vis DRS, TG-DTA and SEM observation. Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra, cyclic voltammograms and luminescence spectra.