Assembly and packing models of [Ti_(6)Co_(12)] ring based on the titanium-capped cobalt clathrochelates

作     者：Hao Fu Shuyu Zhou Xi Fan Lei Zhang Jian Zhang Hao Fu;Shuyu Zhou;Xi Fan;Lei Zhang;Jian Zhang

作者机构：State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of Matter.Chinese Academy of SciencesFuzhou 350002China School of Physical Science and TechnologyShanghai Tech UniversityShanghai 201210China University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2021年第32卷第2期

页      面：923-925页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (NSFC,Nos.21673238 and 21922111) the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB20000000) 

主　　题：Titanium-oxo clusters Wheel-like molecule Coordination self-assembly Heterometallic complexes Clathrochelates 

摘      要：In this work,titanium-capped cobalt clathrochelates have been applied as secondary building units(SBUs) fo r the construction of supramolecular *** heterometallic wheel-like [Ti_(6) Co_(12)] complexes based on cobalt clathrochelates,[C_(6)H_(15)N_(4)]_(2)[TiCo_(2)(μ_(2)-Oipr)(Oipr)_(2)(Dmg)_(3)]_(6)(2,Dmg=dimethy[glyoxime) and H_(6)[TiCo_(2)(μ_(2)-Oipr)(Oipr)_(2)(Dmg)_(3)]_(6)(3),have been successfully synthesized and *** supramolecular stacking modes of these wheels are largely dependent on the applied synthetic conditions,which further impact their gas adsorption properties.