Synthesis and properties of novel nitro-based thermally stable energetic compounds

作     者：Łukasz Gutowski Stanisław Cudziło Łukasz Gutowski;Stanisław Cudziło

作者机构：Military University of TechnologyFaculty of Advanced Technologies and ChemistryGen.Sylwestra Kaliskiego 2 Street00-908WarsawPoland 

出 版 物：《Defence Technology（防务技术）》 (Defence Technology)

年 卷 期：2021年第17卷第3期

页      面：775-784页

核心收录：

学科分类：082604[工学-军事化学与烟火技术] 08[工学] 0826[工学-兵器科学与技术] 

基　　金：Financial support of this work by the Military University of Technology in Warsaw is gratefully acknowledged 

主　　题：Heat resistant explosives Detonation parameters Synthesis Nitration 

摘      要：This paper reviews the achievements in the field of synthesis of new thermally resistant explosive compounds in the years 2009 through 2019. The performance characteristics of these compounds(sensitivity, thermal decomposition parameters, and detonation parameters) were compared with those of 1,3,5-triamino-2,4,6-trinitrobenzene, which still seems to be an unrivalled model of a thermally resistant and generally low-sensitivity explosive material. New thermally stable explosives(TSEs) were found among macromolecular compounds with tri-and dinitrophenyl groups, nitro and amine-nitro derivatives of azoles, and polynitro derivatives of calixarenes. Some of them match TATB in terms of thermal resistance and additionally have higher detonation parameters.