InP quantum dots on g-C_(3)N_(4) nanosheets to promote molecular oxygen activation under visible light

作     者：Yuehan Cao Qian Zheng Zhiqiang Rao Ruiyang Zhang Zhanghui Xie Shan Yu Ying Zhou Yuehan Cao;Qian Zheng;Zhiqiang Rao;Ruiyang Zhang;Zhanghui Xie;Shan Yu;Ying Zhou

作者机构：State Key Laboratory of Oil and Gas Reservoir Geology and ExploitationSouthwest Petroleum UniversityChengdu 610500China The Center of New Energy Materials and TechnologySchool of New Energy and MaterialsSouthwest Petroleum UniversityChengdu 610500China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2020年第31卷第10期

页      面：2689-2692页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070602[理学-大气物理学与大气环境] 0706[理学-大气科学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(No.U1862111) Sichuan Science andTechnology Program(No.2020ZDZX0008) Sichuan Provincial International Cooperation Project(No.2019YFH0164) International Collaboration Project of Chengdu City(No.2017-GH02-00014HZ) Graduate Scientific Research Innovation Foundation of SWPU(No.2019cxyb013) Cheung Kong Scholars Programme of China 

主　　题：InP quantum dots g-C_(3)N_(4)nanosheets Molecular oxygen activation O-O-N-O intermediate Photocatalytic NO removal 

摘      要：Largely limited by the high dissociation energy of the O—O bond,the photocatalytic molecular oxygen activation is highly challenged,which re strains the application of photocatalytic oxidation technology for atmospheric pollutants ***,we design and fabricate the InP QDs/g-C_(3)N_(4) *** introduction of InP QDs promotes the charge transfer within the interface resulting in the effective separation of photo-generated ***,InP QDs greatly facilitates the activation of molecular oxygen and promote the formation of O_(2)·under visible-light illuminatio *** conclusions are identified by experimental and calculation ***,NO can be combined with the O_(2)·to form O—O—N—O intermediate to direct conversion into NO_(3).As a result,the NO removal ratio of g-C_(3)N_(4) has a one fold increase after InP QDs loaded and the generation of NO_(2) is effectively *** wo rk may provide a strategy to design highly efficient materials for molecular oxygen activation.