Low Temperature H_(2) Production from Formic Acid Aqueous Solution Catalyzed on Metal Doped Mo_(2)C

作     者：Shuaishuai Zhu Zhigang Pan Yaqiu Tao Yue Chen 

作者机构：College of Materials Science and EngineeringNanjing Tech UniversityNanjingChina State Key Laboratory of Materials-Oriented Chemical EngineeringNanjing21009China 

出 版 物：《Journal of Renewable Materials》 (可再生材料杂志（英文）)

年 卷 期：2020年第8卷第8期

页      面：939-946页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：financial support of grant from the Natural Science Funds for Young Scholar of China(Grant No.21107049) the priority academic program development of Jiangsu Higher Education Institution(PAPD) 

主　　题：Hydrogen production energy storage and conversion Mo_(2)C/GAC metal doping formic acid decomposition carbon materials 

摘      要：Hydrogen is recognized as a promising energy scours in the close *** hydrogen preparation from formic acid under mild reaction conditions causes extensive ***_(2)C and metal(Fe,Ni,Co,K)doped Mo_(2)C on granular activated carbon(GAC)were prepared and used as heterogeneous catalysts for H2 generation from formic acid on a fixed bed reactor at 100–250°*** formic acid conversions on doped Mo_(2)C-Me/GAC are clearly improved,especially at lower reaction *** doping presents outstanding effect on H2 selectivity and conversion rate compared to Ni and Fe.A 56.3%formic acid conversion was reached on Mo_(2)C-Co/GAC at 100°C,which triples that on Mo_(2)C/GAC at the same *** 150°C,a high formic acid conversion over 90%was reached on Mo_(2)C-Co/*** long lifetime catalysts with no precious metal provide a low cost route to hydrogen production from formic acid.