The Diagenesis of Plant Lipids during the Formation of the Krepoljin Coal Basin(Serbia)—Using Multivariate Statistical Analysis in the Saturated Biomarkers

作     者：Gordana DEVI Branimir JOVANIEVI 

作者机构：Center of ChemistryIChTMNjegoeva 1211000 BelgradeSerbia Faculty of ChemistryUniversity of BelgradePOB 15811001 BelgradeSerbia 

出 版 物：《Acta Geologica Sinica(English Edition)》 (地质学报（英文版）)

年 卷 期：2008年第82卷第6期

页      面：1168-1178页

核心收录：

学科分类：081803[工学-地质工程] 08[工学] 0818[工学-地质资源与地质工程] 

基　　金：supported in part by the Research Fund of the Republic of Serbia 

主　　题：brown coal diagenetic transformations of saturated biomarkers diagenetic transformations of saturated biomarkers steranes diterpanes and triterpanes principal component 

摘      要：The composition of the saturated hydrocarbon fraction of soluble organic matter （bitumen） from the Krepoljin brown coal basin （East Serbia） of Miocene age was investigated. The Krepoljin basin is especially interesting from a geochemical point of view. Namely, by the end of Tertiary Period, the basin was covered by powerful Mesozoic formations of great possibilities, the bedding became hermetically enclosed and protected from subsequent external influences. The nature of early diagenetic processes in the environment with abundant accumulation of organic substance is defined by the molecular content of bitumen through the connections of molecular structures to potential precursors in paleoplant phylla, as well as by the degree of their diagenetic transformations. The hierarchy of parameters based on molecules of saturated hydrocarbons was determined by applying the principal component analysis to the soluble organic matter. The most significant, most ＂loadings＂ values of component CI, are the plant types such as precursors or participants in early diagenetic transformations of steranes Cs27-algal precursor material, Cs28-moulds, Cs29-higher land and water plants; resinous from the group of higher plant gymnosperms （G）; also triterpanes a and β-amirindicotyledonous angiosperms （A） and bacterial and/or terrestrial plants population represented by hopanes/moretanes; as well as the parameters which describe the degree of diagenetic/maturation transformation of precursor biomass, and based on next reactions： （1） shifting of methyl group, influenced by the inorganic sediment constitutents, sterane-rearranged steranes, （2） isomerization in the ring system, ααα→βββ C29 sterane as well as （3） isomerization on chiral center of the side chain sequence R→S C29 sterane S/（S＋R）. Additionally, a pyrite-derived inhibitory effect on the rearrangment of C29 steranes must be taken into account, but not on triterpanes reaction. Non- appearance of statistically important correlations, be