ORGANO-SOLUBLE FLUORINATED POLYIMIDES DERIVED FROM α,α-BIS(4-AMINO-3,5-DIMETHYLPHENYL)-4'-FLUOROPHENYL METHANE AND VARIOUS AROMATIC DIANHYDRIDES

作     者：Jin-gangLiu Yang-xiPeng Hong-shenLi LinFan Shi-yongYang 

作者机构：LaboratoryofAdvancedPolymerMaterialsCenterforMolecularScienceInstituteofChemistryChineseAcademyofSciencesBeijing100080China DepartmentofChemistryHunanLoudiTeacher＇sCollegeLoudi417000China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2005年第23卷第1期

页      面：47-53页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(NSFC)for distinguished Young Scholars(No.59925310) 

主　　题：Fluorinated polyimides Solubility Thermal stability Optical transparency. 

摘      要：Organo-soluble fluorinated polyimides were synthesized by the polycondensation of a new aromatic diamine α,α-bis(4-amino-3,5-dimethylphenyl)-4 -fluorophenyl methane with several aromatic *** one-step polymerizationprocedure was conducted at 180℃ in m-cresol,producing the polyimides with inherent viscosities of 0.68-0.76 dL.g^(-1).Thepolyimides could be soluble not only in polar aprotic solvents,such as N-methyl-2-pyrrolidinone,and N,N-dimethylacetamide,but also in common organic solvents,such as chloroform,cyclopentanone,m-cresol and so *** films show excellent transparency with the UV-Vis cut-off lengths of 310-360 nm and light transmittances ofhigher than 80% in the visible *** addition,the polyimides exhibit good thermal stability with an initial decompositiontemperature(T_d)higher than 530℃ and have more than 60% of residual weight retentions at 700℃.