Solid-state electrochemiluminescence of a novel iridium(Ⅲ) complex

作     者：Shu Quan Sun Qi Jun Song He Fang Yuan Yu Qiang Ding 

作者机构：School of Chemical and Material Engineering Jiangnan University Wuxi 214122 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2008年第19卷第12期

页      面：1509-1512页

核心收录：

学科分类：1007[医学-药学(可授医学、理学学位)] 10[医学] 

基　　金：supported by the National Natural Science Foundation of China (No.20571033) 

主　　题：Solid-state electrochemiluminescence Iridium(m) complex Multi-wall carbon nanotubes 

摘      要：The solid-state ECL behavior of a water-insoluble bis-cyclometalated （pq）2Ir（N-phMA） complex is presented, in which pq is a 2-phenylquinoline anion and N-phMA is N-phenyl methacrylamide, a monoanionic bidentate ligand. The MWNTs/（pq）2Ir（N-phMA） film, MWNTs/Ru（bpy）3^2＋ film and （pq）2Ir（N-phMA） directly modified glassy carbon electrode were fabricated; only the MWNTs/（pq）2Ir（N-phMA） film can produce steady ECL in the presence of tri-n-propylamine as a coreactant.