Synthesis and Characterization of Heterobimetallic Zigzag Chains with a Close-packed Structure Based on Macrocyclic Metalloligands

作     者：SHI Xiao-Ming XIAO Li-Na LI Shu-Jing LI Xiao-Zeng 石晓明;肖利娜;李书静;李孝增

作者机构：College of Chemistry and Chemical EngineeringZhoukou Normal UniversityZhoukou 466001China Department of ChemistrySchool of ScienceTianjin Universityand Collaborative Innovation Center of Chemical Science and EngineeringTianjin 300072China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2020年第39卷第8期

页      面：1465-1474,1359页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the Natural Science Foundation of He’nan Educational Committee of China(17A150056) the National Natural Science Foundation of China(21501203) the Funds of Basic and Advanced Technology Research Project of Henan Province of China(192012310497) the Research Fund for the Doctoral Program of Higher Education of China(Zhoukou Normal University,No.ZKNUB2013003) the Funds of Zhoukou Normal University(ZKNUB115202) 

主　　题：zigzag chain heterobimetallic metalloligand crystal structure fluorescence 

摘      要：Two new heterobimetallic coordination polymers{[Co(NiL)(H2O)3]·4H2O}n(1)and{[Cu(NiL)(H2O)3]·4H2O}n(2)were synthesized based on metalloligand under the same self-assembly conditions.X-ray diffraction analyses reveal that the two compounds involve close-packed zigzag chains,which expand into various three-dimensional supramolecular frameworks through the second interactions such as hydrogen bonds andπ···πstacking *** these two compounds,NiL as a bridging ligand chelates the metal ion nodes via two oxamido carbonyls and carboxylate oxygen *** central Co(Ⅱ)and Cu(Ⅱ)ions in 1 and 2 both exhibit distorted octahedral coordination *** are bridged by macrocyclic oxamido metalloligands fusing the zigzag chains with a‘‘head-to-tail’’*** Ni(Ⅱ)ion in metalloligand is coordinated by four nitrogen atoms with the[NiN4]chromophore exhibiting distorted *** two investigated compounds were further characterized by thermogravimetric analysis and FT-IR *** fluorescent properties of 1 and 2 in the solid state were also investigated.