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Chemical Mechanisms of Prebiotic Chirality Amplification

作     者:Konstantin P.Bryliakov 

作者机构:Novosibirsk State UniversityPirogova 1Novosibirsk 630090Russia Boreskov Institute of CatalysisPr.Lavrentieva 5Novosibirsk 630090Russia 

出 版 物:《Research》 (研究(英文))

年 卷 期:2020年第2020卷第1期

页      面:914-921页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:The author thanks the Russian Science Foundation(#20-13-00032)for financial support 

主  题:Chiral subsequent finding 

摘      要:This review article surveys the recent experimental findings that suggest alternative chemical models of directed chirality amplification at the early,prebiotic *** is believed that the chirality amplification step followed the initial emergence of small enantiomeric imbalance and preceded(as a necessary condition)the occurrence of homochiral biopolymers,assembled from enantiomerically pure building *** work focuses on the chemical nature of possible mechanisms of primordial chirality enhancement,without going into detail of the preceding and subsequent phases of origination of biological homochirality and life on *** mechanisms are discussed through the prism of integrity of biological natural selection and chemical kinetic selection.

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