[Co_3(1,2-S2C6H4)_3(PPh_3)_3]+, A basic triangle unit of some polynuclear molecules

作     者：JIANG, Fei-Long HUANG, Xiao-Ying HONG, Mao-Chun CAO, RongWU, Da-Xu, LIU , Han-QinState Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China 

作者机构：State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter. Chinese Academy of Sciences Fuzhou Fujian 350002 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1994年第12卷第6期

页      面：481-489页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Project supported by the National Natural Science Foundation of China 

主　　题：Polynuclear cobalt thiolate phosphine structure. 

摘      要：[Co3(1,2-S2C6H4)3(PPh3)3][CoBr3(DMF)].sol (1, sol=CHCl3,O(C2H5)2,H2O) was obtained from the reaction of CoBr(PPh3)3 with Na2(S2C6H4) in chloroform. The Co3 core in the cation of 1 exhibits a metal-metal bonded isosceles triangle, in which the two longer Co-Co bonds are both bridged by S2C6H4 ligands on two sides of the triangle plane respectively, while the bottom short Co-Co bond is bridged by the third bidentate S2C6H4 ligand. A series of polynu-clear cobalt cluster compounds with phosphine, thiolate and/or sulphur ligands were prepared by low oxidation state Co+ with thiolates in organic solvents. These tri-, tetra-, hexa-, heptanuclear cluster compounds 1-8 with various types of crystal structures can be viewed as the condensed polynuclear cobalt complexes that the cobalt atom frameworks with sulphur bridged were built through the small triangular units of [Co3S3nL3] (n=1,2) with or without [CoL] (L=PR3, Br, Cl, 5-C5H5) fragments.